N,N′-Dibenzyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide
نویسندگان
چکیده
The phosphoryl and carbonyl groups in the title compound, C(23)H(24)F(2)N(3)O(2)P, are anti to each other. The P atom is in a tetra-hedral coordination environment and the environment of each N atom is essentially planar, the average bond angles at the two N atoms being 119.9 and 119.1°. The H atom of the C(=O)NHP(=O) group is involved in an inter-molecular -P=O⋯H-N- hydrogen bond, forming centrosymmetric dimers.
منابع مشابه
N,N,N′,N′-Tetrabenzyl-N′′-(2,6-difluorobenzoyl)phosphoric triamide
In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P-N bond is longer and the O-P-N angle is contracted compared with the other two P-N bonds and O-P-N angles. The P atom adopts a distorted tetra-hedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzyl-amido groups show sp(2) character wit...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010